At the present time, there is no selective and predictive test for def this paper describes the results of a study aimed at developing a test based on drying and wetting cycles. Expansion results from formation of ettringite crystals of submicrometre size in the paste, the larger. For the purposes of this paper, def will be used to describe the phenomenon by which concrete is damaged by the gradual formation of ettringite within the microstructure of the hardened. The primary formation of ettringite in the initial stages of hydration is seen as beneficial because it enables the setting regulation. In turn, the durability of concrete structures can often be affected by chemical attacks, endangering its performance and safety. Delayed ettringite formation an overview sciencedirect. Evaluation and development of a test method for delayed ettringite. The objective of the research included investigating possible presence of. Delayed ettringite formation def in precast concrete. Reducing expansion due to delayed ettringite formation def is becoming an important issue that must be taken into account, when producing heatcured concrete. Fear, facts, and risks precast structural concrete units are commonly used in bridge construction. Delayed ettringite formation an overview sciencedirect topics.
Delayed ettringite formation def in precast concrete fear, facts and risks bozena czarnecki, ph. The formation of ettringite, however, has no obvious influence on the resistance of fly ash concrete to chloride. Nondestructive evaluation of reinforced concrete structures affected by alkalisilica reaction and delayed ettringite formation. Delayed ettringite because primary ettringite is unstable above 160f, it wont form if curing.
Delayed ettringite formation rocesses and problems 211 furthermore, the pore solution results did not appear to be as glasser et al. It can take up to 20 years for cracking to become apparent. Claims that slow release of sulfate from the clinker can have a similar effect in concrete not thus heated are unsupported. Significance of delayed ettringite formation and damage mechanisms the primary ettringite formation in the initial stage of the hydration is seen as a positive effect because it read more. From this work, a second phase was developed to establish a link between degree of moist map cracking and def. Delayed ettringite formation def is the term used to describe a physicochemical process that may lead to the premature deterioration of a concrete member. Delayed ettringite formation processes and problems.
Preventing alkalisilica reaction and delayed ettringite. Delayed ettringite formation is still an open question. The mechanism of expansion is still the subject of research. The thesis presents the results of an extensive research program on the deterioration of portland cement concrete due to delayed ettringite formation def. Secondary ettringite formation sef is nondestructive. At these temperatures, normal formation of ettringite calcium sulfoaluminate hydrate is impeded until after concrete has hardened.
Fundamental research on secondary ettringite formation. Mpa cement fact sheet 3 delayed etttringite formation in. This phenomenon, referred to as delayed ettringite formation or def, will continue over the years, reducing the concretes life. Effects of calcium sulfate and aluminum crystal forms on. You will be signed out in seconds due to inactivity. Backscatter electron micrograph at higher magnification showing microcracks green arrows from part of the area shown in fig. Download be8252 basic civil and mechanical lecture notes, books, syllabus parta 2 marks with answers be8252 basic civil and mechanical important partb 15 marks questions, pdf books, question bank with answers key. Pdf charactherization of delayed ettringite formation in. There are several types of delayed reactions that cause volume changes generally expansion and cracking. Aci committee 201, guide to durable concrete, aci manual of concrete. Its gradual formation in the cooled, set concrete can lead to expansion and cracking in a process known as delayed ettringite formation def. It is an expansive reaction resulting from the delayed formation of ettringite in a concrete subjected to temperatures above 60c during curing and a moist environment.
The natural formation of ettringite during hydration may be delayed if the concrete. Alkali silica reactions alkali carbonate reactions delayed ettringite formation delayed thaumasite formation delayed hydration. Delayed ettringite formation, 46 september 2002, villars, switzerland 104 figure 9. Delayed ettringite formation request pdf researchgate. Delayed ettringite formation def is a form of internal sulfate attack that is caused by heat curing, moisture, and cement composition. Ettringite formation and the performance of concrete. Delayed ettringite formation def in concrete has been identified in recent as a significant cause of deterioration in some of the reinforced concrete infrastructure in texas. Delayed ettringite formation in concrete jochen stark, katrin bollmann bauhausuniversity weimar germany 1. Delayed ettringite formation def is seen as a form of internal sulfate attack of cementitious materials, caused by early age heating to a temperature higher than 70c. Case studies ofdamage in concrete possibly caused by secondary ettringite formation are examined first. Precastprestressed concrete institute, manual for quality control. To continue working on the website, click stay signed in below.
There have been far fewer documented cases of def than of asr, and prior to this project, there were no published cases in which def was the sole culprit in causing deterioration in an actual field structure. Ettringite solubility and geochemistry of the ca oh al so. Delayed ettringite formation def is a type of internal sulfate attack that occurs in concrete that has reached certain high temperature thresholds in the first few hours of placement. Delayed ettringite formation def is known as the deterioration phenomenon that occurs in mortar or concrete cured at high temperature. Delayed ettringite formation def is a possible autogenous expansive reaction of concrete. Delayed ettringite formation in portland cement products. Delayed ettringite formation is a relatively rare and controversial phenomenon in concrete deterioration, strongly related to the practice of heat curing.
Delayed ettringite formation archives civildigital. Alkali silica reactions alkali carbonate reactions delayed ettringite formation delayed thaumasite formation delayed hydration or dead burned lime or periclase. Claims that slow release of sulfate from the clinker can have a similar effect in concrete not thus. The effects of coatings and sealers used to mitigate alkali. Pdf risk analysis of the delayed ettringite formation in pile caps. The sulfates normally originate in cementitious materials with high sulfate contents. If you need to print pages from this book, we recommend downloading it as a pdf. Durability of concrete in highway facilities bridge engineer. Fillet welds usually have a triangular crosssection. When faces of two members are inclined at an angle, fillet weld is used.
Delayed ettringite formation how is delayed ettringite. Delayed ettringite formation def in precast concrete fear, facts and risks precast structural concrete units are commonly used in bridge construction. Efficient transportation managing the demand 2016 conference and. Characterization of delayed ettringite formation in maryland.
Def delayed ettringite formation a form of sulphate attack where the source of sulphate is internally derived from the cement rather than from an external source. Introduction the problem of durability of concrete with cement as binding material comes more and more to the fore with the increased use of concrete, with the changed production and utilization. Overview of delayed ettringite formation and alkalisilica reaction delayed ettringite formation def and alkalisilica reaction asr are complex mechanisms that can significantly diminish the durability and service life of concrete elements. However, as previously discussed, even though the amount of water applied during the mixing and mellowing process is far too low to solublize sulfates, increased moisture content during mellowing does help optimize the formation of nucleation sites that trigger the development of ettringite. Furthermore, other research showed that ettringite grew well in a solution of aea. The quality of concrete used in the production of girders, deck elements and other bridge elements is expected to be high given that a service life of greater than 75 years is specified for. Evaluation of the potential for delayed ettringite formation in concrete w h r s dayarathne, g s galappaththi, k e s perera, s m a nanayakkara abstract delayed ettringite formation def is commonly referred to as heatinduced internal sulfate attack, which affects the durability and strength of the concrete like in alkalisilica reaction. Over the last decade, a number of reinforced concrete bent caps within houston, texas have exhibited premature concrete damage cracking, spalling and a loss of materialstrength due to alkalisilica reaction asr andor delayed ettringite formation. Characterization of delayed ettringite formation in. Request pdf delayed ettringite formation delayed ettringite formation def can damage concrete that has experienced a temperature above about 70c. Bridge over cooks river at tempe sydney nsw emergency.
If concrete is exposed to water for a long period of time, the primary ettringite will dissolve and recrystallize in voids. Nondestructive evaluation of inservice concrete structures. Effects of calcium sulfate and aluminum crystal forms on the kinetics of ettringite formation. Growth of ettringite crystals opens the crack and damages the cement products. You must not use or adapt this document or rely upon it in any way unless you are providing products or services to a nsw government agency and that agency has expressly authorised you in writing to do so. Nondestructive evaluation of reinforced concrete structures. Lessons learned from structures damaged by delayed ettringite. It has been proposed that def expansion is affected by. Delayed ettringite formation def is a rare but potentially severe form of internal sulfate attack of concrete quillin, 2001. In order to do fillet welding, the angle between joining surfaces shall be within a range of 60 to 120 degrees. The objective of the research included investigating possible presence of def, correlations between the presence of def in castinplace concrete and moist map cracking, and correlations between presence of def in castinplace concrete and air entrainment agents aea.
A certain amount of ettringite hydrous calcium sulfoaluminate forms as part. Def is a result of high early temperatures above 70 o c 80 o c in the concrete which prevents the normal formation of ettringite. Delayed ettringite formation def delayed ettringite formation def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite which is a normal product of early cement hydration. A test method to determine the expansion potential, due to delayed ettringite formation def, of portland cements. Closeup view of a crack on the cross head of the south pier. There have been far fewer documented cases of def than of. Pdf currently, there is an awareness that is critical to assess the durability characteristics of concrete with as much attention as the.
Def is an internal swelling reaction of the concrete that occurs merely in the presence of water without any external ingress of sulfate from the environment in contact with the concrete. The effect of the partial cement substitution with fly ash. Any deterioration of concrete by freezethaw action, alkalisilica. Blast furnace slag addition effects on delayed ettringite. Damage due to the delayed ettringite formation allegedly occurs when material is exposed to temperatures higher than 70c 3,4. A test method to determine the expansion potential, due to delayed ettringite formation def, of portland cements initially moistcured at high temperatures was developed. Delayed ettringite formation def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite which is a normal product of early cement hydration. Pdf delayed ettringite formation in fly ash concrete under. Pdf be8252 basic civil and mechanical lecture notes, books. For more comprehensive information, the authors direct the reader to the american concrete institutes committee 222 documents. Although many papers have been written on case studies of incidences of delayed ettringite formation def, few demonstrate a careful study of the methods of analyses for the presence and concentration of the ettringite. Risk analysis of the delayed ettringite formation in pile.
Delayed ettringite formation a concern for precast concrete. The most important form of internal sulfate attack is delayed ettringite formation def. Alkalisilica reaction asr and delayed ettringite formation def, or combinations of the two, have been found to be the main causes of these problems. This reaction may lay dormant for several years before occurring or may not occur at. Structures of the 2016 annual conference of the transportation association of canada toronto, on abstract. The research investigated the significance of delayed ettringite formation def presences in the maryland bridge inventory. Pdf strategies for prevention of delayed ettringite formation in. Delayed ettnngite formation def is an endogenous reaction which can cause deterioration in concrete.
Def is a result of high early temperatures above 70 o c 80 o c in the concrete which prevents the normal formation. Both have been implicated in the deterioration of numerous structures around the world, including many transportation structures in texas. Ettringite formation and the performance of concrete portland. Perspective overview of delayed ettringite formation and. It was clear that the pore solution sulfate concen trations did not increase substantially at steam curing temperatures. Pdf delayed ettringite formation fami fami academia. In contrast, when temperatures are controlled, ettringite is allowed to form as part of the early formation of cement, thus accommodating expansion while concrete is still green. Investigations have now also been carried out into this formation of new phases, known as late ettringite formation, which takes place under normal ambient. Damage in conjunction with ettringite formation in hardened concrete was first identified in heattreated. Across north america, concrete infrastructure has been susceptible to the premature deterioration caused by alkalisilica reaction asr andor delayed ettringite formation def. It is a recently identified deterioration process which affects the durability and strength of concrete like in alkalisilica reaction asr. Characterization of the ettringite morphologies suggested that lamellar ettringite could be linked to defrelated damage.
Lessons learned from structures damaged by delayed. Delayed ettringite formation in concrete imx technologies. Chemical and petrographic analyses and astm test procedures. The effect of the partial cement substitution with fly ash on. Principal specialist, engineering practice tetra tech eba inc. To fulfil the aim of this study, a portion of cement was replaced by class ffly ash, with three. Although many papers have been written on case studies of incidences of delayed ettringite formation def, few demonstrate a careful study of the methods of analyses for the presence and concentration of the ettringite that has formed. At the present time, there is no selective and predictive test for def this. For the purposes of this paper, def will be used to describe the phenomenon by which concrete is damaged by the gradual formation of ettringite. In this paper, the effect of fly ash on delayed ettringite formation. Delayed ettringite formation, fly ash, portland limestone cement 1. Def is expansion and cracking of concrete associated with the delayed formation of the mineral ettringite a hydrated calcium sulfoaluminate which is a normal product of early cement hydration.
Introduction 1 heatinduced internal sulfate attack is most often referred to as delayed ettringite formation def. Secondary ettringite this is present in hardened, moist concrete. Controlling mass concrete effects in largediameter. A concrete performance test for delayed ettringite formation. Delayed ettringite formation delayed ettringite formation is a less common, but potentially more damaging, cause of distress than asr. The term premature concrete deterioration pcd has been adopted to refer to problems associated with asr and def because it is often difficult to distinguish between them. Examples of sulfate attack include ettringite formation, delayed ettringite formation. The two main chemicals attacks to concrete are attributed to alkaliaggregate reaction aar and the action of sulphates, among which stands out the delayed ettringite formation def delayed ettringite formation. Delayed ettringite formation is also known as secondary ettringite formation sef or late ettringite formation lef. Relationship between delayed ettringite formation and delayed expansion in massive shrinkagecompensating concrete.
Fillet weld for steel connections guidelines for fillet. This report is part of a research project, txdot project. Pdf the use of chemical admixtures to prevent delayed. Alkalisilica reaction and delayed ettringite formation. While reduced durability and service life are legitimate concerns, it is also important to. Since 2006, research funded by the texas department of transportation txdot has evaluated the use of coatings and sealers for mitigating expansion due to alkalisilica reaction asr andor delayed ettringite formation def in hardened concrete. The time temper ature pro file for all temperatures wa s shown in figure 3 2 as expected. Controlling ettringite formation the national academies press. Alkalisilica reaction asr and delayed ettringite formation def are expansive reactions that can lead to the premature deterioration of concrete structures. Study of asraffected and defaffected structures as well as testing and evaluation results of eliminating components. Pdf with many large scale civil engineering construction projects being undertaken, there is a possibility to find large concrete pours in thick. It can affect materials that have experienced temperatures higher than about 65 c at early age.
Arrows indicate microcracks that are filled with a clear, gellike material red, a void filled with ettringite green, and the outer surface of the core blue. Expansion of cement mortars made with eight different portland cements was investigated. Unfortunately, this book cant be printed from the openbook. Delayed ettringite formation def in precast concrete fear. In this paper, the effect of fly ash on delayed ettringite formation of heatcured cementbased mortars was investigated.
1534 196 657 74 71 1281 1239 260 209 542 99 1321 439 304 381 1218 1528 1580 1306 96 1154 1060 544 758 667 160 957 1661 655 498 1492 962 1346 1162 1102 449 750 245 639 1183 245